Oxidative deamination of primary amines: selective synthesis of geminal dihalides
MP Doyle, B Siegfried
Index: Doyle,M.P.; Siegfried,B. Journal of the Chemical Society, Chemical Communications, 1976 , p. 433 - 434
Full Text: HTML
Citation Number: 0
Abstract
SELECTIVE oxidative conversion of unbranched primary amines into aldehydes or aldehyde derivatives has not previously been achieved. Two approaches to this problem are envisaged : dehydrogenation of amines, and oxidative deamination. Considerable interest has recently been focused on the dehydrogenation of amine ligands in pro- moting amine oxidations by transition nieta1s.l However, dehydrogenation of unbranched primary amines does not terminate at ...
Related Articles:
[Brinker, Udo H.; Lin, Guoying; Xu, Linxiao; Smith, William B.; Mieusset, Jean-Luc Journal of Organic Chemistry, 2007 , vol. 72, # 22 p. 8434 - 8451]
[Seyferth,D. et al. Journal of Organic Chemistry, 1970 , vol. 35, p. 1989 - 1993]
Dihalocarbene Insertion into CH Bonds of Cycloalkanes1
[Seyferth,D.; Cheng,Y.-M. Synthesis, 1974 , p. 114 - 115]
γ??Strahlen??induzierte Addition von chlorierten Methanen an Cyclische Olefine
[Schwarz,A. et al. Chemische Berichte, 1968 , vol. 101, p. 1601 - 1613]