Reactions of Ar+ with halocarbons and of I+ with CF3I

…, JM Van Doren, AA Viggiano, JF Paulson

Index: Morris, Robert A.; Doren, Jane M. Van; Viggiano, A. A.; Paulson, John F. Journal of Chemical Physics, 1992 , vol. 97, # 1 p. 173 - 179

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Citation Number: 19

Abstract

The gas phase reactions of Ar+ with the halocarbons CF3Cl, CF3Br, CF3I, CF4, C2F6, and C2F4 have been studied using a variable temperature??selected ion flow tube (VT??SIFT) instrument operated at 298 and 500 K. Rate constants and product branching percentages were measured at both temperatures. Ar+ reacts at the collisional rate with all of the above neutrals at both 298 and 500 K. The reactions with CF3X yield CF+ 3 and CF2X+ for all X ( ...

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