Journal of organometallic chemistry

Derives mono et bicycliques du bore tetracoordonne et des α-aminodiacides: reactions avec divers nucleophiles

B Garrigues, M Mulliez

Index: Garrigues, Bernard; Mulliez, Michel Journal of Organometallic Chemistry, 1986 , vol. 314, p. 19 - 24

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Citation Number: 7

Abstract

Abstract Water, methanol and isopropylamine react with mono-and bi-cyclic boroxazolidones (2a and 3a) by attacking the boron atom and not the CO group, with formation of aminodiacid and tricoordinated boron compounds. The boron compounds undergo successive B C cleavage catalysed by the aminodiacid released.

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