Molybdenum nitrosyl complexes and their application in catalytic imine hydrogenation reactions

A Dybov, O Blacque, H Berke

Index: Dybov, Alexander; Blacque, Olivier; Berke, Heinz European Journal of Inorganic Chemistry, 2011 , # 5 p. 652 - 659

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Citation Number: 5

Abstract

Abstract The reaction between [Mo (CO) 4 (NO)(ClAlCl 3)] and the sterically hindered diphosphanes (P∩ P) 1, 3-bis (diisopropylphosphanyl) propane (dippp, a), 1, 2-bis ( diisopropylphosphanyl) ethane (dippe, b), 1, 1′-bis (diisopropylphosphanyl) ferrocene (dippf, c) and 1, 2-bis (dicyclohexylphosphanyl) ethane (dcype, d) produced the chlorides [Mo (P∩ P)(CO) 2 (NO) Cl](1a–1d), which were transformed into the corresponding ...

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