On the concerted mechanism of the ene reaction of singlet molecular oxygen with olefins. An ab-initio mo study
K Yamaguchi, T Fueno, I Saito, T Matsuura, KN Houk
Index: Yamaguchi, K.; Fueno, T.; Saito, I.; Matsuura, T.; Houk, K. N. Tetrahedron Letters, 1981 , vol. 22, p. 749 - 752
Full Text: HTML
Citation Number: 13
Abstract
Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Ab-initio MO (4-31G) calculations were performed for the reaction of propene with singlet molecular oxygen. The theoretical resultindicates that the concerted mechanism involves a model A-type transition state. ... K. Yamaguchi, S. Yabushita, T. Fueno and KN Houk, to be published.
Related Articles:
Kinetics and product study of the self-reactions of allyl and allyl peroxy radicals at 296 K
[Jenkin, Michael E.; Murrells, Timothy P.; Shalliker, Stephen J.; Hayman, Garry D. Journal of the Chemical Society, Faraday Transactions, 1993 , vol. 89, # 3 p. 433 - 446]
Synthese und Eigenschaften von Allylhydroperoxyd
[Seyfarth,H.E. et al. Angewandte Chemie, 1965 , vol. 77, p. 1078]
[Neta, P.; Huie, R. E.; Mosseri, S.; Shastri, L. V.; Mittal, J. P.; et al. Journal of Physical Chemistry, 1989 , vol. 93, # 10 p. 4099 - 4104]