Hydrolytic Reactions of p-Nitrophenyl Esters in Reversed Micellar Systems
H Fujii, T Kawai, H Nishikawa
Index: Fujii,H. et al. Bulletin of the Chemical Society of Japan, 1979 , vol. 52, p. 1978 - 1982
Full Text: HTML
Citation Number: 11
Abstract
Hydrolytic reactions of several p-nitrophenyl esters were studied with and without catalysts in reversed micellar systems consisting of sodium octanoate, 1-hexanol and water. Hydrolytic rate constants become very large as compared with those in aqueous solutions, increasing with decrease in the molar ratio of water to sodium octanoate (R-value). The results of kinetic measurements were discussed in terms of the behavior of water ...
Related Articles:
[Wynn; Caldwell; Robinson; Beamer; Bauguess Journal of Pharmaceutical Sciences, 1982 , vol. 71, # 7 p. 772 - 776]
A remarkable enhancement of the rate of ester thiolysis by synthetic amphiphile vesicles
[Cuccovia, Iolanda M.; Quina, Frank H.; Chaimovich, Hernan Tetrahedron, 1982 , vol. 38, # 7 p. 917 - 920]