Synthesis of main??chain poly (carbazole) s via CuAAC

Z Chen, DR Dreyer, Z Wu, KM Wiggins…

Index: Chen, Zheng; Dreyer, Daniel R.; Wu, Zong-Quan; Wiggins, Kelly M.; Jiang, Zhenhua; Bielawski, Christopher W. Journal of Polymer Science, Part A: Polymer Chemistry, 2011 , vol. 49, # 6 p. 1421 - 1426

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Citation Number: 10

Abstract

Abstract The synthesis and characterization of a novel family of main-chain carbazole- containing polymers using copper-catalyzed azide-alkyne cycloaddition chemistry is reported. The reactions were performed under mild conditions using readily available copper catalysts and ligands, which afforded polymeric products with M ws up to 18 kDa. Using a range of techniques, the polymers were found to exhibit a glass transition ...