Synthetic Communications
Synthesis of 1-Formyl 1, 1-Dialkylmethylphosphonates
MP Teulade, P Savignac
Index: Teulade, Marie-Paule; Savignac, Philippe Synthetic Communications, 1987 , vol. 17, # 2 p. 125 - 136
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Citation Number: 8
Abstract
Abstract Preparation of 1-formyl 1, 1-dialkylmethylphosphonates is described. A carbanionic route is provided by the condensation of α-lithio α, α-disubstituted methylphosphonates with ethylformate whereas a carbocationic route provided by the acid catalyzed rearrangement of β, β-disubstituted epoxyethylphosphonates is re-evaluated.
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