New data on the malonic ester phosphorylation

…, EV Minaeva, AK Shibaeva, AK Sal'keeva

Index: Sal'keeva; Taishibekova; Nurmaganbetova; Minaeva; Shibaeva Russian Journal of General Chemistry, 2011 , vol. 81, # 10 p. 2198 - 2199

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Abstract

Later was shown [2] that the reaction of chlorophosphate with sodium malonic ester occurs by an O-phosphorylation scheme. The phosphorylation of malonic ester with diethyl chlorophosphite in the presence of triethylamine was shown to give a C-phosphorylation product, which was converted into diethyl dicarboethoxymethylphosphonate I [3].

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