Implications of the rotationally resolved spectra of the alkoxy radicals for their electronic structure
SC Foster, YC Hsu, CP Damo, X Liu…
Index: Foster, Stephen C.; Hsu, Yen-Chu; Damo, Cristino P.; Liu, Xianming; Kung, Chung-Yi; Miller, Terry A. Journal of Physical Chemistry, 1986 , vol. 90, # 26 p. 6766 - 6769
Full Text: HTML
Citation Number: 38
Abstract
Laser excitation spectra of several alkoxy radicals including methoxy, ethoxy, vinoxy, and isopropoxy have been recorded at low temperature in a supersonic free jet expansion. These spectra in all cases show well-resolved rotational structure. These structures are used to determine the symmetry of the two electronic states involved in the transitions. The symmetries so determined are rationalized in terms of simple molecular orbital theory.
Related Articles:
[Scaiano; Barra; Krzywinski; Sinta; Calabrese Journal of the American Chemical Society, 1993 , vol. 115, # 18 p. 8340 - 8344]
Temperature??dependent kinetics studies of the reactions of C2H5O2 and n??C3H7O2 radicals with NO
[Eberhard; Howard International Journal of Chemical Kinetics, 1996 , vol. 28, # 10 p. 731 - 740]
[Khatoon, T.; Edelbuettel-Einhaus, J.; Hoyermann, K.; Wagner, H. Gg. Berichte der Bunsen-Gesellschaft, 1989 , vol. 93, p. 626 - 632]
Photodissociation of alkyl nitrites in a molecular beam. Primary and secondary reactions
[Effenhauser, C. S.; Felder, P.; Huber, J. Robert Journal of Physical Chemistry, 1990 , vol. 94, # 1 p. 296 - 302]