Free-radical selective functionalization of 1, 4-naphthoquinones by perfluorodiacyl peroxides
…, A Baggioli, R Soave, F Venturini, SV Meille, I Wlassics…
Index: Wlassics, Ivan; Barchiesi; Sala Journal of Fluorine Chemistry, 2003 , vol. 123, # 1 p. 119 - 126
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Abstract
Abstract Perfluoroalkyl radicals, generated by thermal decomposition of perfluorodiacyl peroxides, react selectively with quinone rings of 1, 4-naphthoquinones. In the presence of a non-conjugated alkene such as 1-hexene, perfluoroalkyl radicals add to the double bonds of
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