Thieme Chemistry Journal Awardees-Where are They Now? Dibutyltin Dimethoxide Catalyzed N-Nitrosoaldol Reaction of Alkenyl Trichloroacetate
A Yanagisawa, Y Izumi, S Takeshita
Index: Yanagisawa, Akira; Izumi, Youhei; Takeshita, Satoshi Synlett, 2009 , # 5 p. 716 - 719
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Citation Number: 6
Abstract
Abstract Nitrosoaldol reaction between alkenyl trichloroacetates and nitrosobenzene has been achieved using dibutyltin dimethoxide as a catalyst, which is regenerated in the presence of methanol. The corresponding α-hydroxyamino ketones (N-adducts) have exclusively formed not only from cyclic alkenyl trichloroacetates but also from acyclic ones.
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