Microwave accelerated aza-Claisen rearrangements

…, P Čonka, E Gajdošíková, CO Kappe

Index: Gonda, Jozef; Martinkova, Miroslava; Zadrosova, Andrea; Sotekova, Monika; Raschmanova, Jana; Conka, Patrik; Gajdosikova, Eva; Kappe, C. Oliver Tetrahedron Letters, 2007 , vol. 48, # 39 p. 6912 - 6915

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Citation Number: 25

Abstract

The microwave-assisted thermal aza-Claisen rearrangement of allylic imidates and thiocyanates to the corresponding amides and isothiocyanates is investigated. Significant accelerations of the rearrangement of allylic imidates to amides and of allylic thiocyanates to isothiocyanates in comparison with standard thermal reactions is observed.

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