N??Heterocyclic Benzhydrylamines as New N, N??Bidentate Ligands in Palladium Complexes: Synthesis, Characterization and Catalytic Activity

V Terrasson, D Prim, J Marrot

Index: Terrasson, Vincent; Prim, Damien; Marrot, Jerome European Journal of Inorganic Chemistry, 2008 , # 17 p. 2739 - 2745

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Citation Number: 11

Abstract

Abstract The synthesis of new N, N-bidentate ligands based on a π-deficient N-heterocyclic benzhydrylamine core is described. The corresponding air-stable palladium complexes are obtained in high yields and fully characterized by NMR spectroscopy and X-ray structure determination. These new phosphane-free catalytic systems proved efficient in the Suzuki– Miyaura reaction, enabling us to obtain biaryl products in good yields, also for reactions ...