Tetrahedron

Transition-metal catalyzed silylzincation and silylalumination of acetylenic compounds

K Wakamatsu, T Nonaka, Y Okuda, W Tückmantel…

Index: Wakamatsu, Kuni; Nonaka, Tsuyoshi; Okuda, Yasuhiro; Tueckmantel, Werner; Oshima, Koichiro; et al. Tetrahedron, 1986 , vol. 42, # 16 p. 4427 - 4436

Full Text: HTML

Citation Number: 51

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Dialkyl(dimethylphenylsilyl)zinclithium and trialkyl(dimethylphenylsilyl)aluminiumlithium add effectively to internal acetylenes as well as terminal ones in the presence of transition-metal catalysts to provide vinylsilanes with high stereo- and regioselectivities.

Related Articles:

Anti-hydroalumination of Homo-and bishomopropargyl alcohols

[Ma, Shengming; Liu, Fang; Negishi, Ei-Ichi Tetrahedron Letters, 1997 , vol. 38, # 22 p. 3829 - 3832]

1-lithio-1-benzenesulfinyl-2-trimethylsilylethane as a 2-trimethylsilylvinyl anion equivalent in reactions with aldehydes, ketones and epoxides

[Hsiao, C-N.; Shechter, H. Tetrahedron Letters, 1983 , vol. 24, # 23 p. 2371 - 2374]

1-lithio-1-benzenesulfinyl-2-trimethylsilylethane as a 2-trimethylsilylvinyl anion equivalent in reactions with aldehydes, ketones and epoxides

[Hsiao, C-N.; Shechter, H. Tetrahedron Letters, 1983 , vol. 24, # 23 p. 2371 - 2374]

Synthesis of Geminal Dimetal-Substituted Terminal Alkenes Utilizing a Cuprate Rearrangement: Toward an Efficient and General Access to Trisubstituted Olefins

[Menez, Patrick Le; Brion, Jean-Daniel; Lensen, Nathalie; Chelain, Evelyne; Pancrazi, Ange; Ardisson, Janick Synthesis, 2003 , # 16 p. 2530 - 2534]

More Articles...