Derivatives of a weakly basic amine: N, N-bis (2-fluoro-2, 2-dinitroethyl) amine

WH Gilligan, ME Sitzmann

Index: Gilligan, William H.; Sitzman, Michael E. Journal of Chemical and Engineering Data, 1982 , vol. 27, # 1 p. 97 - 99

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Citation Number: 5

Abstract

The preparation of derivatives of 4 is outlined in Scheme I. The proton NMR spectrum of 14 indicated that it was a mixture of isomers, which differed In the position of the trlfluoroacetyl group. An attempt to remove the trifluoroacetyl group from 14 by hydrolysis was complicated by the fact that the fluorodinitromethyl group on the ring also proved to be susceptible to hydrolysis.