Journal of Fluorine Chemistry

Catalytic hydrogenolysis of carbon-fluoride bonds: π bond participation mechanism

M Hudlicky

Index: Butina, D.; Hudlicky, M. Journal of Fluorine Chemistry, 1980 , vol. 16, p. 301 - 324

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Citation Number: 39

Abstract

Abstract A new mechanism with the participation of π bonds is proposed to account for a relatively easy hydrogenolysis of carbon-fluoride bonds in catalytic hydrogenation of allylic, vinylic, benzylic and aromatic fluorides. This cyclic mechanism can also underlie some