The reaction of ozonides from mono-substituted alkenes with stabilized phosphorus ylides

YS Hon, L Lu, SY Li

Index: Hon, Yung-Son; Lu, Ling; Li, Shyh-Yuan Journal of the Chemical Society, Chemical Communications, 1990 , # 22 p. 1627 - 1628

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Citation Number: 8

Abstract

Ozonides derived from mono-substituted alkenes react with methyl (triphenylphosphorany1idene)acetate or (triphenylphosphorany1idene)acetophenone to form trans-cu,p-unsaturated esters or ketones, respectively, in high yields. ... Ozonolysis is an important tool for the cleavage of carbon- carbon double bonds.' The intermediate ozonides can be reduced in situ to give the corresponding carbonyl compounds or alcohols by treating them with ...