Non-acid catalytic acetalisation of aldehydes with diols in ionic liquids

F Zhang, DQ Xu, SP Luo, BY Liu…

Index: Zhang, Fan; Xu, Dan-Qian; Luo, Shu-Ping; Liu, Bao-You; Du, Xiao-Hua; Xu, Zhen-Yuan Journal of Chemical Research, 2004 , # 11 p. 773 - 774

Full Text: HTML

Citation Number: 7

Abstract

The acetalisation of aldehydes with diols to corresponding 1, 3-dioxolanes has been accomplished using ionic liquids as catalyst and reaction media. In the reaction process the removal of water produced and other catalysts were not necessary. High conversion and good selectivity were obtained when using HMImBF4, which could be easily recycled and reused.

Related Articles:

Acrolein acetals as allyl cation precursors in the ionic Diels-Alder reaction

[Gassman, Paul G.; Singleton, Daniel A.; Wilwerding, James J.; Chavan, Subhash P. Journal of the American Chemical Society, 1987 , vol. 109, # 7 p. 2182 - 2184]

More Articles...