The First General Method for Stille Cross??Couplings of Aryl Chlorides
AF Littke, GC Fu
Index: Littke, Adam F.; Fu, Gregory C. Angewandte Chemie - International Edition, 1999 , vol. 38, # 16 p. 2411 - 2413
Full Text: HTML
Citation Number: 292
Abstract
Abstract A “one-two punch” comprising two commercially available reagents, PtBu 3 and CsF, provides a practical and general solution for a long-standing limitation of the Stille reaction—the inability to couple inexpensive and readily available aryl chlorides [Eq.(1); R 1= OMe, NH 2, o-Me, etc.; R= vinyl, allyl, Ph, Bu, etc.].
Related Articles:
Ionic liquid-promoted, highly regioselective Heck arylation of electron-rich olefins by aryl halides
[Mo, Jun; Xu, Lijin; Xiao, Jianliang Journal of the American Chemical Society, 2005 , vol. 127, # 2 p. 751 - 760]
A novel hydrophobic fluorous ionic liquid for ligand-free Mizoroki–Heck reaction
[Gaikwad, Dipak S.; Park, Yoonkook; Pore, Dattaprasad M. Tetrahedron Letters, 2012 , vol. 53, # 24 p. 3077 - 3081]