Dimethyldioxirane reactions: Rate acceleration due to intramolecular H??bonding
RW Murray, H Gu
Index: Murray, Robert W.; Gu, Hong Journal of Physical Organic Chemistry, 1996 , vol. 9, # 11 p. 751 - 758
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Citation Number: 13
Abstract
Abstract Absolute rate studies were carried out on a series of C (SINGLE BOND) H insertion reactions of dimethyldioxirane (1a). The substrates were chosen so that the distance between a single tertiary C (SINGLE BOND) H bond and an OH group could be varied. The measured rate constants indicate that a rate acceleration occurs when the distance between the reacting C (SINGLE BOND) H bond and the OH group permits intramolecular H- ...
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