Tetrahedron

A comparative study on the photo-induced arylation of β-dicarbonyl compounds by arylazosulfides and its use in the synthesis of methyl labeled 2-arylpropionic acids

M Tona, F Sánchez-Baeza, A Messeguer

Index: Tona, Merce; Sanchez-Baeza, Francisco; Messeguer, Angel Tetrahedron, 1994 , vol. 50, # 27 p. 8117 - 8126

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Citation Number: 10

Abstract

A comparative study on the arylation of β-dicarbonyl derivatives (acetylacetone, methyl acetoacetate and dimethyl malonate) by using the photo-induced decomposition of arylazosulfides is presented. The arylazosulfides used contained the aryl moieties related to Ketoprofen or Ibuprofen and the reaction was performed following the procedure reported by Dell'Erba et al.(Tetrahedron, 1991, 47, 333). From the arylazosulfides assayed, only those ...

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