Copper (I)??Catalyzed Cascade Synthesis of 2??Arylsulfanyl??arylcyanamides

SK Sahoo, L Jamir, S Guin…

Index: Sahoo, Santosh K.; Jamir, Latonglila; Guin, Srimanta; Patel, Bhisma K. Advanced Synthesis and Catalysis, 2010 , vol. 352, # 14-15 p. 2538 - 2548

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Citation Number: 31

Abstract

Abstract We have developed a ligand-assisted copper (I)-catalyzed two sequential heteroarylation sequence. An intramolecular S-arylation is followed by an intermolecular N- arylation leading to the direct synthesis of N-aryl-2-aminobenzothiazoles. In most cases however, the 2-arylsulfanyl-arylcyanamide was the major product obtained via an intramolecular C [BOND] S bond formation, associated with C [BOND] S bond breakage, ...

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