Conversion of Carbon-Sulfur Linkages into Carbon–Silicon Ones via Reductive Silylation. Preparation of Silyl Enol Ethers of Acyltrimethylsilanes
I Kuwajima, A Mori, M Kato
Index: Kuwajima, Isao; Mori, Akio; Kato, Masahiro Bulletin of the Chemical Society of Japan, 1980 , vol. 53, # 9 p. 2634 - 2638
Full Text: HTML
Citation Number: 14
Abstract
Reductive cleavage of carbon–sulfur linkages of silyl enol ethers of thiocarboxylic S-esters can be induced by treatment with sodium or potassium–sodium alloy in the presence of chlorotrimethylsilane, and the corresponding silyl enol ethers of acyltrimethylsilanes can be prepared in high yields.
Related Articles:
[Reich, Hans J.; Holtan, Ronald C.; Bolm, Carsten Journal of the American Chemical Society, 1990 , vol. 112, # 14 p. 5609 - 5617]
Synthesis and reactivity of iron carbonyl complexes of α, β-unsaturated acyl silanes
[Thomas, Susan E.; Tustin, Gary J.; Ibbotson, Arthur Tetrahedron, 1992 , vol. 48, # 36 p. 7629 - 7640]
Synthesis and reactivity of iron carbonyl complexes of α, β-unsaturated acyl silanes
[Thomas, Susan E.; Tustin, Gary J.; Ibbotson, Arthur Tetrahedron, 1992 , vol. 48, # 36 p. 7629 - 7640]
Synthesis and reactivity of iron carbonyl complexes of α, β-unsaturated acyl silanes
[Thomas, Susan E.; Tustin, Gary J.; Ibbotson, Arthur Tetrahedron, 1992 , vol. 48, # 36 p. 7629 - 7640]