Reactions of organic compounds in adsorbed monolayers. I. Ozonation of 3, 7-dimethyloctyl acetate
ALJ Beckwith, CL Bodkin, T Duong
Index: Beckwith,A.L.J. et al. Australian Journal of Chemistry, 1977 , vol. 30, p. 2177 - 2188
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Citation Number: 17
Abstract
Abstract Oxidation with ozone of 3, 7-dimethyloctyl acetate (7) adsorbed on silica gel, alumina or barium sulphate proceeds in good yield and affords mainly the 7-hydroxy compound (8) and the 7-nor-ketone (9). Minor products include the 3-alcohol (10) and the 3, 7-diol (11). The reaction involves interaction of gaseous ozone with the adsorbed organic substrate. The relative yields of the various products are related to the substrate loading. ...
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