New Stereoselective Synthesis of (Z)-α-Iodovinylsilanes via One-Pot Iododesilylation/Isomerization of 1, 1-Bis (silyl) alk-1-enes
P Pawluć, M Madalska, G Hreczycho, B Marciniec
Index: Pawluc, Piotr; Madalska, Martyna; Hreczycho, Grzegorz; Marciniec, Bogdan Synthesis, 2008 , # 22 p. 3687 - 3691
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Citation Number: 5
Abstract
Abstract Synthetically useful (Z)-2-aryl-1-iodo-1-silylethenes were prepared in good to excellent yields via one-pot monoiododesilylation/isomerization of readily accessible 2-aryl- 1, 1-bis (silyl) ethenes using N-iodosuccinimide or bis (pyridine) iodonium tetrafluoroborate under mild conditions.
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