Organometallics

Synthesis and Properties of Calcium Tetraorganylalanates with [Me4− n AlPh n]− Anions

S Krieck, H Görls, M Westerhausen

Index: Krieck, Sven; Goerls, Helmar; Westerhausen, Matthias Organometallics, 2008 , vol. 27, # 19 p. 5052 - 5057

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Citation Number: 20

Abstract

The reaction of PhCaI with AlPh3 in THF yields the ion pair [(thf) 5CaI][AlPh4]. The variability of this reaction is striking when AlMe3 was employed as the Lewis acid. A Schlenk equilibrium and methyl/phenyl exchange reactions take place, yielding alanates of the type [(thf) 6Ca][Me4− n AlPh n] 2.

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