Regioselective synthesis of the tricyclic core of lateriflorone
…, H Li, BG Vong, SH Kim, EA Theodorakis
Index: Tisdale, Eric J.; Li, Hongmei; Vong, Binh G.; Kim, Sun Hee; Theodorakis, Emmanuel A. Organic Letters, 2003 , vol. 5, # 9 p. 1491 - 1494
Full Text: HTML
Citation Number: 26
Abstract
An efficient synthetic approach to the tricyclic core 8 of lateriflorone is described. Essential to the synthesis was the implementation of a biomimetic tandem Claisen/Diels-Alder reaction that produced the desired tricyclic scaffold as a single isomer. A rationalization of the excellent regio and stereoselectivity of this transformation is also proposed.
Related Articles:
Total synthesis of seco-lateriflorone
[Tisdale, Eric J.; Vong, Binh G.; Li, Hongmei; Kim, Sun Hee; Chowdhury, Chinmay; Theodorakis, Emmanuel A. Tetrahedron, 2003 , vol. 59, # 35 p. 6873 - 6887]
Total synthesis of seco-lateriflorone
[Tisdale, Eric J.; Vong, Binh G.; Li, Hongmei; Kim, Sun Hee; Chowdhury, Chinmay; Theodorakis, Emmanuel A. Tetrahedron, 2003 , vol. 59, # 35 p. 6873 - 6887]
Total synthesis of seco-lateriflorone
[Tisdale, Eric J.; Vong, Binh G.; Li, Hongmei; Kim, Sun Hee; Chowdhury, Chinmay; Theodorakis, Emmanuel A. Tetrahedron, 2003 , vol. 59, # 35 p. 6873 - 6887]
Total synthesis of seco-lateriflorone
[Tisdale, Eric J.; Vong, Binh G.; Li, Hongmei; Kim, Sun Hee; Chowdhury, Chinmay; Theodorakis, Emmanuel A. Tetrahedron, 2003 , vol. 59, # 35 p. 6873 - 6887]