Zur Kenntnis der Reaktionsfähigkeit des unsubstituierten Thiomorpholins und alkylsubstituierter Thiomorpholine. 3. Mitt

F Asinger, A Saus, J Hartig, P Rasche…

Index: Asinger,F. et al. Monatshefte fuer Chemie, 1979 , vol. 110, p. 767 - 789

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Citation Number: 7

Abstract

Abstract A new synthesis of thiomorpholine by ring closure of β-chloro-β′-aminodiethylene- sulfide with potassium hydroxide is reported. Numerous reactions of thiomorpholine (1) and, especially, 2-methyl-3-ethyl-thiomorpholine (2) are described such as acylation, diacylation (3–43), reactions with sulfonic acid chlorides (44–52), isocyanates (53–61, 70–75), diisocyanates (62–66, 76–78) and isothiocyanates (67–69, 79–82), alkylation reactions ( ...