Chemistry–A European Journal

Shape??Persistent (Pt??salphen) 2 Phosphorescent Coordination Frameworks: Structural Insights and Selective Perturbations

Z Guo, SM Yiu, MCW Chan

Index: Guo, Zhengqing; Yiu, Shek-Man; Chan, Michael C. W. Chemistry - A European Journal, 2013 , vol. 19, # 27 p. 8937 - 8947

Full Text: HTML

Citation Number: 18

Abstract

Abstract The development of molecular frameworks derived from binuclear platinum (II) aromatic Schiff base (salphen) complexes and their supramolecular chemistry have been undertaken. A series of axially rotating (Pt-salphen) 2 luminophores, tethered in a cofacial manner by a rigid linker (xanthene, 1; dibenzofuran, 2; biphenylene, 3), was synthesized in which the O (salphen) groups are potentially amenable for guest-binding. The molecular ...