Palladium??Catalyzed Ortho??Selective C F Activation of Polyfluoroarenes with Triethylsilane: A Facile Access to Partially Fluorinated Aromatics

Z Chen, CY He, Z Yin, L Chen, Y He…

Index: Chen, Zhao; He, Chun-Yang; Yin, Zengsheng; Chen, Liye; He, Yi; Zhang, Xingang Angewandte Chemie - International Edition, 2013 , vol. 52, # 22 p. 5813 - 5817 Angew. Chem., 2013

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Citation Number: 41

Abstract

Owing to the unique characteristics of fluorine that often lead to profound changes in physical, chemical, and biological properties of organic molecules when it is incorporated,[1] partially fluorinated aromatics play an important role in life and materials sciences.[2] However, synthetic access to these fluorinated compounds is difficulties [3] and there is only limited commercial availability of fluoroaromatic sources. One attractive approach to ...