An efficient conversion of nitroaromatics and aromatic amines to tertiary amines in one-pot way
YJ Jung, JW Bae, ES Park, YM Chang, CM Yoon
Index: Jung, Yeon Joo; Bae, Jong Woo; Park, Eun Soo; Chang, Yu Mi; Yoon, Cheol Min Tetrahedron, 2003 , vol. 59, # 51 p. 10331 - 10338
Full Text: HTML
Citation Number: 18
Abstract
Reductive alkylation and reductive methylation of aromatic primary amines with carbonyls and 37% formaldehyde using decaborane in one-pot way gave the corresponding tertiary amines in high yields. The reaction condition was extended for the reduction of nitroaromatic using decaborane and Pd/C followed by the reductive alkylation and reductive methylation using decaborane to give the corresponding tertiary amines in high yields.
Related Articles:
[Yeon Joo Jung; Jong Woo Bae; Choon-Ock Maing Yoon; Byung Woo Yoo; Cheol Min Yoon Synthetic Communications, 2001 , vol. 31, # 22 p. 3417 - 3421]
N-Dealkylation-N-nitrosation of tertiary aromatic amines by N-butyl nitrite
[Verardo, Giancarlo; Giumanini, Angelo G.; Strazzolini, Paolo Tetrahedron, 1991 , vol. 47, # 37 p. 7845 - 7852]