Synthesis and Solid-State Polymerization of. OMEGA.-(1, 3-Butadiynyl) Substituted 1-Alkanol and Alkanoic Acid.

…, H Matsuda, M Otsuka, N Kikuchi, K Hayamizu…

Index: Okada, Shuji; Matsuda, Hiro; Otsuka, Masaaki; Kikuchi, Naoto; Hayamizu, Kikuko; et al. Bulletin of the Chemical Society of Japan, 1994 , vol. 67, # 2 p. 455 - 461

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Citation Number: 13

Abstract

ω-(1, 3-Butadiynyl) substituted 1-alkanol and alkanoic acid were synthesized and their polymerization behavior in crystals and in Langmuir–Blodgett (LB) films were investigated. Polymerization, using UV or γ-ray irradiation or thermal treatment, resulted in red-or golden- colored polymers. Since the absorption edge in the visible spectra of these polymers appeared at shorter wavelengths than those of the well known blue-colored ...