On the reactivity of metal and organometallic halides toward R3Sn O SnR3 systems
K Singhal, R Mishra, P Raj
Index: Singhal, Kiran; Mishra, Rahul; Raj, Prem Heteroatom Chemistry, 2009 , vol. 20, # 5 p. 278 - 283
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Citation Number: 2
Abstract
Abstract Interaction of metallic salts (M= Hg, Sb, and Te) with bis (triorganotin) oxide,(R 3 Sn) 2 O, where (R= C 6 H 5, p-CH 3 C 6 H 4, and cyclo-C 6 H 11) at room temperature proceeded with the simultaneous cleavage of the Sn [BOND] C and Sn [BOND] O bonds, invariably yielding R 2 SnO along with other products. Thus the treatment of HgX 2 (X= Cl, CN, SCN) with (R 3 Sn) 2 O resulted in the formation of polymeric diorganotin oxide R 2 ...
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