Heterocycles

The first and simple total synthesis of cappariloside A1

M Somei, F Yamada

Index: Somei, Masanori; Yamada, Fumio Heterocycles, 2000 , vol. 53, # 7 p. 1573 - 1578

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Citation Number: 10

Abstract

抄録: A lithium hydroxide promoted simple glycosylation of 4-hydroxyindole-3-acetonitrile with 2, 3, 4, 6-tetra-O-acetyl-aD-glucopyranosyl bromide was developed. Utilizing the method, the first and five steps total synthesis of cappariloside A was achieved from indole-3- carbaldehyde in 41% overall yield.