Heteroatom Chemistry

Synthesis and characterization of some novel triphenylarsenic (V) derivatives of monofunctional bidentate 2, 2??disubstituted benzothiazoline ligands

PK Sharma, AK Rai, Y Singh

Index: Sharma, Pankaj K.; Rai; Singh, Yashpal Heteroatom Chemistry, 2007 , vol. 18, # 1 p. 76 - 80

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Citation Number: 3

Abstract

Abstract A series of triphenylarsenic (V) derivatives Ph 3 As (OPr i)[SC 6 H 4 N: C (R) CH 2 C (O) R′] have been synthesized by the reactions of triphenylarsenic (V)-isoproproxide, Ph 3 As (OPr i) 2 with the corresponding 2, 2-disubstituted benzothiazolines of the type equation image (where R= CH 3, R′= CH 3 (1); R= CH 3, R′= C 6 H 5 (2); R= CH 3, R′= 4-CH 3 C 6 H 4 (3); R= CH 3, R′= 4-ClC 6 H 4 (4); and R= CF 3, R′= C 6 H 5 (5)) in equimolar ...