Novel Chloride to Bromide Exchange: Preparation of 1-Bhomoalkyl Carbonates
JP Senet, G Sennyey, GP Wooden
Index: Senet, Jean-Pierre; Sennyey, Gerard; Wooden, Gary P. Synthetic Communications, 1988 , vol. 18, # 13 p. 1525 - 1530
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Abstract
Abstract A new method is described for the synthesis of 1-bromoalkyl carbonates which consists of reacting the corresponding 1-chloroalkyl carbonate with a volatile electrophilic bromine containing reagent (E-Br) and a catalyst. The equilibrium is driven to product by removal of the E-C1 formed.
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