Mechanism of nitration of nitrogen-containing heterocyclic N-acetonyl derivatives. General approach to the synthesis of N-dinitromethylazoles

…, AB Bruskin, MI Kanishchev, AT Baryshnikov

Index: Semenov; Shevelev; Bruskin; Kanishchev; Baryshnikov Russian Chemical Bulletin, 2009 , vol. 58, # 10 p. 2077 - 2096

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Citation Number: 7

Abstract

Abstract A general synthetic procedure for the synthesis of N-dinitromethyl derivatives of nitrogen-containing heterocycles has been developed. The procedure includes the destructive nitration of heterocyclic N-acetonyl derivatives of tetrazoles, 1, 2, 4-and 1, 2, 3- triazoles, pyrazoles, imidazoles and their bicyclic analogs, as well as imides of carboxylic and sulfonic acids and substituted hydrazines with mixtures of sulfuric and nitric acids. The ...