Cross-coupling of organosilanes with organic halides mediated by a palladium catalyst and tris (diethylamino) sulfonium difluorotrimethylsilicate

Y Hatanaka, T Hiyama

Index: Hatanaka, Yasuo; Hiyama, Tamejiro Journal of Organic Chemistry, 1988 , vol. 53, # 4 p. 918 - 920

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Citation Number: 520

Abstract

Summary: In the presence of tris (diethy1amino) sulfonium difluorotrimethylsilicate (TASF) and allylpalladium chloride dimer as a catalyst, organosilicon compounds like vinyl-, ethynyl- , and allylsilanes react with such organic halides as aryl, vinyl, and allyl halides to give the corresponding coupled products in synthetically useful yields in a stereospecific and chemoselective manner.