Selenium stablized anions. Conversion of β-hydroxy selenides into olefins

HJ Reich, F Chow

Index: Reich,H.J.; Chow,F. Journal of the Chemical Society, Chemical Communications, 1975 , p. 790 - 791

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Citation Number: 27

Abstract

Summary Sulphonylation of p-hydroxy selenides, pre- PhSeNa,8 or by reaction of cc-lithio selenides 9J0 and selen- pared by addition of organometallic compounds to oxideslO with carbonyl compounds. We have used ali- carbonyl compounds, results in reductive elimination to phatic selenides as starting materials since these are readily give olefins under unusually mild conditions. ... THE addition of functionalized organolithium reagents to