Hydrophosphorylation of terminal alkynes catalyzed by palladium

…, TM Dolgina, GN Bondarenko, IP Beletskaya

Index: Gulykina; Dolgina; Bondarenko; Beletskaya Russian Journal of Organic Chemistry, 2003 , vol. 39, # 6 p. 797 - 806

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Citation Number: 26

Abstract

Abstract A series of new 1-aryl-, 1-heteroaryl-, and 1-alkylethenylphosphonates was prepared by hydrophosphorylation of terminal acetylenes catalyzed by palladium. A stable in air complex Pd 2 (dba) 3· CHCl 3 was applied as catalyst. The reaction mechanism is discussed.