Synthesis and binding properties of dendritic oxybathophenanthroline ligands towards copper (II)
…, G Bernhard, P Comba, G Rajaraman…
Index: Stephan, Holger; Geipel, Gerhard; Bernhard, Gert; Comba, Peter; Rajaraman, Gopalan; Hahn, Uwe; Voegtle, Fritz European Journal of Inorganic Chemistry, 2005 , # 22 p. 4501 - 4508
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Abstract
Abstract Dendritic oxybathophenanthroline ligands (generation 0 to 3) have been synthesized by treatment of 4, 7-bis (4′-hydroxyphenyl)-1, 10-phenanthroline with the corresponding Fréchet-type dendrons carrying a benzylic bromide function at the focal point. The complexation of copper (II) has been studied by liquid–liquid extraction using the radioisotope 64 Cu and time-resolved laser-induced fluorescence spectroscopy (TRLFS) ...
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