The Journal of Organic Chemistry

Evaluation of the mode of neighboring group participation by divalent sulfur

H Kwart, D Drayer

Index: Kwart,H.; Drayer,D. Journal of Organic Chemistry, 1974 , vol. 39, # 15 p. 2157 - 2166

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Citation Number: 10

Abstract

Two types of neighboring group participation in intramolecular displacement reactions are distinguished by reference to intermolecular SN1 and SN~ processes. The thiomethyl (in o- allylthioanisole) and methoxyl (in O-allylanisole) groups were compared with the H in allylbenzene as reference in respect to their participation as neighboring groups in a series of electrophilic and free radical chain addition reactions of the double bond. The addition ...