Carbohydrate research

Stereochemische aspekte in zusammenhang mit der synthese von 2, 6-anhydro-1-desoxy-1-nitroalditolen

A Förtsch, H Kogelberg, P Köll

Index: Foertsch, Armin; Kogelberg, Heide; Koell, Peter Carbohydrate Research, 1987 , vol. 164, p. 391 - 402

Full Text: HTML

Citation Number: 20

Abstract

Abstract 2, 6-Anhydro-1-deoxy-1-nitroalditols were prepared in good yields by known procedures via addition of nitromethane to d-glucose, d-mannose, d-galactose, d-xylose, d- lyxose and l-arabinose, followed by a cyclization step in boiling water. In the case of d- ribose, a mixture of pyranoid and furanoid anhydroalditols was isolated by different methods in relatively poor yields, at variance with recent reports by other authors. Establishment of ...