Tetrahedron

Aluminum dodecatungstophosphate (AlPW 12 O 40) as a non-hygroscopic Lewis acid catalyst for the efficient Friedel–Crafts acylation of aromatic compounds under …

H Firouzabadi, N Iranpoor, F Nowrouzi

Index: Firouzabadi, Habib; Iranpoor, Nasser; Nowrouzi, Farhad Tetrahedron, 2004 , vol. 60, # 48 p. 10843 - 10850

Full Text: HTML

Citation Number: 81

Abstract

Stable and non-hygroscopic aluminum dodecatungstophosphate (AlPW12O40), which is prepared easily from cheap and commercially available compounds was found to be an effective catalyst for Friedel–Crafts acylation reactions using carboxylic acids, acetic anhydride and benzoyl chloride in the absence of solvent under mild reaction conditions.

Related Articles:

Asymmetric transfer hydrogenation of 1-naphthyl ketones by an ansa-Ru (II) complex of a DPEN-SO2N (Me)-(CH2) 2 (η6-p-Tol) combined ligand

[Kisic, Andrea; Stephan, Michel; Mohar, Barbara Organic Letters, 2013 , vol. 15, # 7 p. 1614 - 1617]

An efficient method for aromatic Friedel-Crafts acylation reactions

[Khodaei, Mohammad Mehdi; Bahrami, Kiumars; Shahbazi, Fomeida Chemistry Letters, 2008 , vol. 37, # 8 p. 844 - 845]

Mixed sulfonic-carboxylic anhydrides. III. Reactions with aromatic ethers and aromatic hydrocarbons

[Karger,M.H.; Mazur,Y. Journal of Organic Chemistry, 1971 , vol. 36, # 4 p. 540 - 544]

The use of aliphatic acid anhydrides in the preparation of ketones by the Friedel and Crafts reaction

[Noller; Adams Journal of the American Chemical Society, 1924 , vol. 46, p. 1892]

More Articles...