Kinetics of thermal and hydrolytic decomposition of 1, 3, 4-dioxazol-2-one derivatives

S Mitra, CG Overberger

Index: Mitra, Smarajit; Overberger, C.G. Journal of Organic Chemistry, 1988 , vol. 53, # 12 p. 2674 - 2677

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Abstract

The synthesis of model compounds 6 and 6 for the homopolymers of vinyl-and isopropenydioxazol-% ones is described. These compounds are hydrolyzed to hydroxamic acids which can be estimated colorimetrically by complexation with Fe3+. The hydrolylitic rates have been determined and the thermolysis rates were followed by measuring undecomposed dioxazolones by the colorimetric method. The isopropyldioxazolone was ...