Double bond migration in S allyl systems catalysed by [RuClH (CO)(PPh 3) 3]

…, S Krompiec, T Bieg, S Baj, K Skutil, A Chrobok

Index: Kuznik, Nikodem; Krompiec, Stanislaw; Bieg, Tadeusz; Baj, Stefan; Skutil, Krzysztof; Chrobok, Anna Journal of Organometallic Chemistry, 2003 , vol. 665, # 1-2 p. 167 - 175

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Citation Number: 42

Abstract

Reactions of S allyl systems (allyl sulphides of R S allyl type, where R= Et, allyl, Ph, Me3C, Ph3C, as well as of allyl phenyl sulphoxide, allyl phenyl sulphone, 2, 5-dihydro-1, 1- dioxothiophene) with [RuClH (CO)(PPh3) 3] and other ruthenium compounds have been investigated. Double-bond migration was observed in the case of allyl trityl sulphide, allyl t- butyl sulphide and both sulphones, that is, where co-ordinating properties of sulphur were ...