Interplay between the palladium (II) ion, unidentate ligands and hydroxyl groups from a bidentate ligand in a new complex that catalyses hydration and alcoholysis of …

NV Kaminskaia, IA Guzei, NM Kostić

Index: Kaminskaia, Natalia V.; Guzei, Ilia A.; Kostic, Nenad M. Journal of the Chemical Society - Dalton Transactions, 1998 , # 22 p. 3879 - 3885

Full Text: HTML

Citation Number: 22

Abstract

Palladium (II) complexes containing the bidentate ligand 3, 6-dithiaoctane-1, 8-diol (dtod) and chloride anions (1) or solvent molecules (2) as two unidentate ligands were synthesized and characterized by 1H and 13C NMR spectroscopy. The complex 1, which is the precursor to the catalyst 2, was also characterized by elemental analysis and X-ray crystallography. The crystal structure of 1 shows square planar co-ordination of two sulfur and two chloride ...