Transition Metal Chemistry

Molecular structure and linkage isomerization in copper (II) complexes containing N, N-dialkyl-N′-benzylethylenediamine and thiocyanate ligands: a combined …

H Golchoubian, S Koohzad

Index: Golchoubian, Hamid; Koohzad, Sara Transition Metal Chemistry, 2014 , vol. 39, # 3 p. 327 - 335

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Abstract

Abstract A combined experimental and computational study of three thiocyanate-Cu (II) complexes with general formula [Cu (L n) 2 (NCS)] ClO 4,(L 1= N, N-dimethyl, N′-benzyl- ethylenediamine, L 2= N, N-diethylyl, N′-benzyl-ethylenediamine, L 3= N, N-diisopropylyl, N′-benzyl-ethylenediamine) was carried out. The compounds were synthesized and structurally characterized by physico-chemical and spectroscopic methods. X-ray ...