Tetrahedron

Reactions of cupric halides with organic compounds—VIII: Reactions of 9-acylanthracenes

DC Nonhebel, JA Russell

Index: Nonhebel,D.C.; Russell,J.A. Tetrahedron, 1970 , vol. 26, p. 2781 - 2786

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Citation Number: 6

Abstract

9-Acylanthracenes undergo reaction with cupric halides in chlorobenzene to give 9-acyl-10- halogenoanthracenes together with 9-halogeno-and 9, 10-dihalogenoanthracenes. The products arise from ligand-transfer reactions of the cupric halide and the 9-acylanthracene at the 9-and 10-positions. 9-Acetylanthracene gives 9-bromoacetylanthracene on reaction with cupric bromide in ethyl acetate-chloroform.